1,3-Diisopropylbenzene → 2-[3,5-Di(propan-2-yl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

HRID 1491244

反応式

HRID 1491244 の反応式
CC(C)c1cccc(C(C)C)c1>C1=CCCC=CCC1.C1=CCCC=CCC1.C1CCOC1.CC(C)(C)c1ccnc(-c2cc(C(C)(C)C)ccn2)c1.CC1(C)OB(B2OC(C)(C)C(C)(C)O2)OC1(C)C.C[OH2+].C[OH2+].[Ir].[Ir]>CC(C)c1cc(B2OC(C)(C)C(C)(C)O2)cc(C(C)C)c1

参加物

6

反応物 1

HCID 74501,3-Diisopropylbenzene

生成物 1

HCID 534290492-[3,5-Di(propan-2-yl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane収率 83%

試薬・触媒・溶媒 4

HCID 2733548Bis(pinacolato)diborane試薬HCID 42491874,4'-Di-tert-butyl-2,2'-bipyridyl試薬HCID 76001521Bis(1,5-cyclooctadiene)dimethoxydiiridium触媒HCID 8028Tetrahydrofuran溶媒

反応条件

温度
25 °C

出典と根拠

ORDレコード
ord-bac43139b767409ebec942f4b010d100
出典データセット
Borylation dataset from Roche

関連ノート

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