18-Crown-6 → (4S,5R)-tert-butyl 4-(fluoromethyl)-2,2-dimethyl-5-(4-(3-(methylsulfonylmethyl)isoxazol-5-yl)phenyl)oxazolidine-3-carboxylate
反応式
[F:1][CH2:2][C@@H:3]1[C@@H:7]([C:8]2[CH:13]=[CH:12][C:11]([C:14]3[O:18][N:17]=[C:16]([CH2:19]OS(C)(=O)=O)[CH:15]=3)=[CH:10][CH:9]=2)[O:6][C:5]([CH3:26])([CH3:25])[N:4]1[C:27]([O:29][C:30]([CH3:33])([CH3:32])[CH3:31])=[O:28].[CH3:34][S:35]([O-:37])=[O:36].[Na+].C1OCCOCCOCCOCCOCCOC1>C(#N)C>[F:1][CH2:2][C@@H:3]1[C@@H:7]([C:8]2[CH:9]=[CH:10][C:11]([C:14]3[O:18][N:17]=[C:16]([CH2:19][S:35]([CH3:34])(=[O:37])=[O:36])[CH:15]=3)=[CH:12][CH:13]=2)[O:6][C:5]([CH3:25])([CH3:26])[N:4]1[C:27]([O:29][C:30]([CH3:32])([CH3:31])[CH3:33])=[O:28]参加物
5
