Sodium Hydroxide → Silver(1+) dibenzyl phosphate

HRID 1525135ノート

反応式

HRID 1525135 の反応式
[P:1]([O-:19])([O:11][CH2:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)([O:3][CH2:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)=[O:2].[OH-].[Na+].[N+]([O-])([O-])=O.[Ag+:26]>O>[P:1]([O-:19])([O:3][CH2:4][C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1)([O:11][CH2:12][C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)=[O:2].[Ag+:26]

参加物

5

反応物 3

HCID 14798Sodium HydroxideHCID 24470Silver NitrateHCID 4193600Dibenzylphosphate

生成物 1

HCID 13248164Silver(1+) dibenzyl phosphate収率 82.6%

試薬・触媒・溶媒 1

HCID 962Water溶媒2 回

実験手順

Dibenzyl phosphate (2.78 g, 10 mmol) in water (40 mL) was cooled in an ice bath. Subsequently, 1N NaOH was added while shaking the flask until the pH of solution was about 7. The solid dissolved almost completely. Then silver nitrate (1.89 g, 11 mmol) in water (20 mL) was added slowly. After adding, the resulting solid was collected by filtration and washed with water. The solid was dried in vacuum over phosphorus pentoxide to yield silver dibenzyl phosphate (3.18 g) (yield, 82.5%) as a white solid.

後処理

  1. dissolutionThe solid dissolved almost completely
  2. additionAfter adding
  3. filtrationthe resulting solid was collected by filtration
  4. washwashed with water
  5. dry with materialThe solid was dried in vacuum over phosphorus pentoxide

出典と根拠

ORDレコード
ord-3a37b49b2b3f4dc0b9fe1b0ad6857f72
出典データセット
uspto-grants-2015_07
特許番号
US09079928B2

反応ノート

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