Allyl Mercaptan → HCID 9794329、化合物

HRID 1585988ノート

反応式

HRID 1585988 の反応式
[Na].[CH2:2]([SH:5])[CH:3]=[CH2:4].[CH3:6][O:7][C:8]1[N:9]=[N:10][C:11](Cl)=[C:12]([CH3:15])[C:13]=1[CH3:14]>CO>[CH3:6][O:7][C:8]1[N:9]=[N:10][C:11]([S:5][CH2:2][CH:3]=[CH2:4])=[C:12]([CH3:15])[C:13]=1[CH3:14]

参加物

5

反応物 3

HCID 13367Allyl MercaptanHCID 5360545SodiumHCID 212176653-Chloro-6-methoxy-4,5-dimethylpyridazine

生成物 1

HCID 9794329HCID 9794329、化合物

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

0.23 g(0.01 mol) of metallic sodium was dissolved in 30 ml of absolute methanol and then mixed with 0.93 ml(0.01 mol) of allylmercaptan. To this mixture was added 1.73 g(0.01 mol) of 3-methoxy-4,5-dimethyl-6-chloropyridazine obtained from Preparation 5. The reaction solution was refluxed for one hour and then treated according to the same manner as Example 1 to obtain the title compound as a freezing pale white crystal.

後処理

  1. customobtained from Preparation 5
  2. temperatureThe reaction solution was refluxed for one hour
  3. additiontreated

出典と根拠

ORDレコード
ord-ecd857d5b5914f38a47db573be880587
出典データセット
uspto-grants-1999_08
特許番号
US05942511

反応ノート

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