Allyl Mercaptan → HCID 10198535、化合物
反応式
[Na].[CH2:2]([SH:5])[CH:3]=[CH2:4].[CH3:6][O:7][C:8]1[C:17]2[C:12](=[CH:13][CH:14]=[CH:15][CH:16]=2)[C:11](Cl)=[N:10][N:9]=1>CO>[CH3:6][O:7][C:8]1[C:17]2[C:12](=[CH:13][CH:14]=[CH:15][CH:16]=2)[C:11]([S:5][CH2:2][CH:3]=[CH2:4])=[N:10][N:9]=1参加物
5
実験手順
0.23 g(0.01 mol) of metallic sodium was dissolved in 30 ml of absolute methanol and then mixed with 0.93 ml(0.01 mol) of allylmercaptan. To this mixture was added 1.95 g(0.01 mol) of 1-methoxy-4-chlorophthalazine obtained from Preparation 7. The reaction solution was refluxed for one hour and then treated according to the same manner as Example 1 to obtain the title compound as a freezing pale white crystal.
後処理
- customobtained from Preparation 7
- temperatureThe reaction solution was refluxed for one hour
- additiontreated
出典と根拠
- ORDレコード
- ord-fed89c9846f7463d81bd519cb371368c
- 出典データセット
- uspto-grants-1999_08
- 特許番号
- US05942511
反応ノート
読み込み中…