Allyl Mercaptan → HCID 21217666、化合物

HRID 1585991ノート

反応式

HRID 1585991 の反応式
[Na].[CH2:2]([SH:5])[CH:3]=[CH2:4].[CH2:6]([O:8][C:9]1[N:10]=[N:11][C:12](Cl)=[CH:13][CH:14]=1)[CH3:7]>CO>[CH2:6]([O:8][C:9]1[N:10]=[N:11][CH:12]=[CH:13][C:14]=1[S:5][CH2:2][CH:3]=[CH2:4])[CH3:7]

参加物

5

反応物 3

HCID 13367Allyl MercaptanHCID 2615793-Chloro-6-ethoxypyridazineHCID 5360545Sodium

生成物 1

HCID 21217666HCID 21217666、化合物

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

0.57 g(0.025 mol) of metallic sodium was dissolved in 40 ml of absolute methanol and then mixed with 2.49 ml(0.025 mol) of allylmercaptan. To this mixture was added 3.96 g(0.025 mol) of 3-ethoxy-6-chloropyridazine. The reaction solution was refluxed for 24 hours and then treated according to the same manner as Example 1 to obtain the title compound as a freezing pale white crystal.

後処理

  1. temperatureThe reaction solution was refluxed for 24 hours
  2. additiontreated

出典と根拠

ORDレコード
ord-b78a413db91a4584925d9e7c9d806fe9
出典データセット
uspto-grants-1999_08
特許番号
US05942511

反応ノート

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