Allyl Mercaptan → HCID 9794857、化合物

HRID 1585994ノート

反応式

HRID 1585994 の反応式
[Na].[CH2:2]([SH:5])[CH:3]=[CH2:4].[CH2:6]([O:8][C:9]1[C:18]2[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=2)[C:12](Cl)=[N:11][N:10]=1)[CH3:7]>CO>[CH2:6]([O:8][C:9]1[C:18]2[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=2)[C:12]([S:5][CH2:2][CH:3]=[CH2:4])=[N:11][N:10]=1)[CH3:7]

参加物

5

反応物 3

HCID 13367Allyl MercaptanHCID 5360545SodiumHCID 212176601-Chloro-4-ethoxyphthalazine

生成物 1

HCID 9794857HCID 9794857、化合物

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

0.23 g(0.01 mol) of metallic sodium was dissolved in 100 ml of absolute methanol and then mixed with 0.93 ml(0.01 mol) of allylmercaptan. To this mixture was added 2.09 g(0.01 mol) of 1-ethoxy-4-chlorophthalazine obtained from Preparation 10. The reaction solution was refluxed for 3 hours and then treated according to the same manner as Example 1 to obtain the title compound as a freezing white crystal.

後処理

  1. customobtained from Preparation 10
  2. temperatureThe reaction solution was refluxed for 3 hours
  3. additiontreated

出典と根拠

ORDレコード
ord-410766fcd3fc46009dbb63f29386785c
出典データセット
uspto-grants-1999_08
特許番号
US05942511

反応ノート

読み込み中…