Allyl Mercaptan → Pyridazine, 3-(2-propenylthio)-6-propoxy-
反応式
[Na].[CH2:2]([SH:5])[CH:3]=[CH2:4].[CH2:6]([O:9][C:10]1[N:11]=[N:12][C:13](Cl)=[CH:14][CH:15]=1)[CH2:7][CH3:8]>CO>[CH2:6]([O:9][C:10]1[N:11]=[N:12][C:13]([S:5][CH2:2][CH:3]=[CH2:4])=[CH:14][CH:15]=1)[CH2:7][CH3:8]参加物
5
実験手順
1.15 g(0.05 mol) of metallic sodium was dissolved in 75 ml of absolute methanol and then mixed with 4.98 ml(0.05 mol) of allylmercaptan. To this mixture was added 8.63 g(0.05 mol) of 3-(n-propoxy)-6-chloropyridazine. The reaction solution was refluxed for 24 hours and then treated according to the same manner as Example 1 to obtain the title compound as a pale yellow oily residue.
後処理
- temperatureThe reaction solution was refluxed for 24 hours
- additiontreated
出典と根拠
- ORDレコード
- ord-0a471fdb725042d98a5fc22967d9fb5c
- 出典データセット
- uspto-grants-1999_08
- 特許番号
- US05942511
反応ノート
読み込み中…