Allyl Mercaptan → HCID 10130734、化合物

HRID 1585997ノート

反応式

HRID 1585997 の反応式
[Na].[CH2:2]([SH:5])[CH:3]=[CH2:4].[CH2:6]([O:10][C:11]1[N:12]=[N:13][C:14](Cl)=[CH:15][CH:16]=1)[CH2:7][CH2:8][CH3:9]>CO>[CH2:6]([O:10][C:11]1[N:12]=[N:13][C:14]([S:5][CH2:2][CH:3]=[CH2:4])=[CH:15][CH:16]=1)[CH2:7][CH2:8][CH3:9]

参加物

5

反応物 3

HCID 13367Allyl MercaptanHCID 2528253-butoxy-6-chloropyridazineHCID 5360545Sodium

生成物 1

HCID 10130734HCID 10130734、化合物

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

1.15 g(0.05 mol) of metallic sodium was dissolved in 75 ml of absolute methanol and then mixed with 4.98 ml(0.05 mol) of allylmercaptan. To this mixture was added 9.33 g(0.05 mol) of 3-(n-butoxy)-6-chloropyridazine. The reaction solution was refluxed for 24 hours and then treated according to the same manner as Example 1 to obtain the title compound as a pale yellow oil.

後処理

  1. temperatureThe reaction solution was refluxed for 24 hours
  2. additiontreated

出典と根拠

ORDレコード
ord-c653d76dda1245b391a28e607699980c
出典データセット
uspto-grants-1999_08
特許番号
US05942511

反応ノート

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