Allyl Mercaptan → HCID 21217670、化合物

HRID 1586001ノート

反応式

HRID 1586001 の反応式
[Na].[CH2:2]([SH:5])[CH:3]=[CH2:4].[CH2:6]([O:11][C:12]1[N:13]=[N:14][C:15](Cl)=[CH:16][CH:17]=1)[CH2:7][CH:8]([CH3:10])[CH3:9]>CO>[CH2:6]([O:11][C:12]1[N:13]=[N:14][C:15]([S:5][CH2:2][CH:3]=[CH2:4])=[CH:16][CH:17]=1)[CH2:7][CH:8]([CH3:10])[CH3:9]

参加物

5

反応物 3

HCID 13367Allyl MercaptanHCID 2528263-Chloro-6-(3-methylbutoxy)pyridazineHCID 5360545Sodium

生成物 1

HCID 21217670HCID 21217670、化合物

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

1.15 g(0.05 mol) of metallic sodium was dissolved in 150 ml of absolute methanol and then mixed with 4.98 ml(0.05 mol) of allylmercaptan. To this mixture was added 10.03 g(0.05 mol) of 3-isopentyloxy-6-chloropyridazine. The reaction solution was refluxed for 24 hours and then treated according to the same manner as Example 1 to obtain the title compound as a pale yellow oil.

後処理

  1. temperatureThe reaction solution was refluxed for 24 hours
  2. additiontreated

出典と根拠

ORDレコード
ord-05db89f258dd44e4a3c0f0f4bce562e8
出典データセット
uspto-grants-1999_08
特許番号
US05942511

反応ノート

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