Allyl Mercaptan → HCID 10219981、化合物

HRID 1586002ノート

反応式

HRID 1586002 の反応式
[Na].[CH2:2]([SH:5])[CH:3]=[CH2:4].[OH:6][CH2:7][CH2:8][O:9][C:10]1[N:11]=[N:12][C:13](Cl)=[CH:14][CH:15]=1>CO>[OH:6][CH2:7][CH2:8][O:9][C:10]1[N:11]=[N:12][C:13]([S:5][CH2:2][CH:3]=[CH2:4])=[CH:14][CH:15]=1

参加物

5

反応物 3

HCID 13367Allyl MercaptanHCID 5360545SodiumHCID 14343567122913-80-8

生成物 1

HCID 10219981HCID 10219981、化合物

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

0.23 g(0.01 mol) of metallic sodium was dissolved in 30 ml of absolute methanol and then mixed with 1.00 ml(0.01 mol) of allylmercaptan. To this mixture was added 1.75 g(0.01 mol) of 3-(2-hydroxyethoxy)-6-chloropyridazine. The reaction solution was refluxed for 24 hours and then treated according to the same manner as Example 1 to obtain the title compound as a pale white needle crystal.

後処理

  1. temperatureThe reaction solution was refluxed for 24 hours
  2. additiontreated

出典と根拠

ORDレコード
ord-fd34e192f5ca401d8e966cabc950c911
出典データセット
uspto-grants-1999_08
特許番号
US05942511

反応ノート

読み込み中…