Sodium Hydroxide → HCID 19008520、化合物

HRID 1586879ノート

反応式

HRID 1586879 の反応式
[C:1]1([S:11]([OH:13])=[O:12])[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][CH:2]=1.[OH-].[Na+].[CH:16]([S:18](Cl)(=[O:20])=[O:19])=[CH2:17]>O.C(#N)C>[CH:16]([S:18](=[O:20])(=[O:19])[S:11]([C:1]1[C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=[CH:3][CH:2]=1)(=[O:13])=[O:12])=[CH2:17]

参加物

6

反応物 3

HCID 14798Sodium HydroxideHCID 533445Ethenesulfonyl chlorideHCID 108887691-Naphthalenesulfinic acid

生成物 1

HCID 19008520HCID 19008520、化合物収率 24.9%

試薬・触媒・溶媒 2

HCID 962Water溶媒3 回HCID 6342Acetonitrile溶媒

実験手順

15 ml of water was added to 9.6 g of 1-naphthalene sulfinic acid and a solution of 2 g of sodium hydroxide in 5 ml of water was added to the mixture. To the solution there was added a solution of 6.3 g of vinylsulfonyl chloride in 20 ml of acetonitrile at room temperature with stirring and the mixture was stirred at room temperature for additional 24 hours. The reaction solution was poured into 300 ml of water, the resulting precipitates were recovered through filtration and recrystallized from a mixed solvent of benzene and ethanol to give 3.5 g of vinyl-1-naphthyldisulfone.

後処理

  1. stirringthe mixture was stirred at room temperature for additional 24 hours
  2. customthe resulting precipitates
  3. filtrationwere recovered through filtration
  4. customrecrystallized from a mixed solvent of benzene and ethanol

出典と根拠

ORDレコード
ord-ef3aa95e744f47fdb97902e8ad05518b
出典データセット
uspto-grants-1993_06
特許番号
US05216105

反応ノート

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