Dimethylformamide → Methacrylamide

HRID 1587465

反応式

HRID 1587465 の反応式
[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[C:9]([O:14][CH:15]1[CH2:20][CH2:19][CH2:18][CH2:17][CH2:16]1)(=[O:13])[C:10]([CH3:12])=[CH2:11].[C:21]([NH2:26])(=[O:25])[C:22]([CH3:24])=[CH2:23].CN(C)C=O>>[CH3:23][CH:22]1[CH2:24][CH:10]([CH3:11])[C:9](=[O:13])[NH:26][C:21]1=[O:25].[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[C:9]([O:14][CH:15]1[CH2:20][CH2:19][CH2:18][CH2:17][CH2:16]1)(=[O:13])[C:10]([CH3:12])=[CH2:11].[C:21]([NH2:26])(=[O:25])[C:22]([CH3:24])=[CH2:23]

参加物

8

反応物 4

HCID 6228DimethylformamideHCID 6595MethacrylamideHCID 7501StyreneHCID 7561Cyclohexyl methacrylate

生成物 4

HCID 6595MethacrylamideHCID 7501StyreneHCID 7561Cyclohexyl methacrylateHCID 2647903,5-Dimethylpiperidine-2,6-dione

反応条件

温度
90 °C

実験手順

A 2,4-dimethylglutarimide, styrene, and cyclohexyl methacrylate containing polymer was prepared by the techniques of copolymerization and glutarimidization. Accordingly an interpolymer of styrene, cyclohexyl methacrylate, and methacrylamide was prepared. In a 1.5 liter, glass reactor fitted with inlet tubes, nitrogen pad, and stirrer, styrene 29 g, cyclohexyl methacrylate 225 g, and methacrylamide 122 g, were introduced, along with 50 percent based o monomer weight of N,N-dimethylformamide solvent. 250 ppm of a peroxide initiator 1,1-bis(t-butylperoxy)cyclohexane was introduced and the reactor heated to 80-100° C. with stirring. Reaction was continued only a short time period (10-20 percent conversion) to prevent polymer compositional drift and possible degeneration of optical properties. The polymer was recovered by precipitation in methanol.

後処理

  1. additionwere introduced, along with 50 percent
  2. customReaction
  3. customThe polymer was recovered by precipitation in methanol

出典と根拠

ORDレコード
ord-16767af77c4f400e8ffc23813fb49c22
出典データセット
uspto-grants-1993_06
特許番号
US05218068

関連ノート

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