Pyridine → HCID 59317126、化合物
反応式
[Br:1][C:2]1[C:3]([O:19][CH2:20][C:21]2[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=2)=[CH:4][C:5]([O:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[C:6]([CH:10]=1)[C:7](Cl)=[O:8].[NH2:27][C:28]1[C:29]([CH3:34])=[CH:30][CH:31]=[CH:32][CH:33]=1.N1C=CC=CC=1>ClCCl>[Br:1][C:2]1[C:3]([O:19][CH2:20][C:21]2[CH:26]=[CH:25][CH:24]=[CH:23][CH:22]=2)=[CH:4][C:5]([O:11][CH2:12][C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)=[C:6]([CH:10]=1)[C:7]([NH:27][C:28]1[CH:33]=[CH:32][CH:31]=[CH:30][C:29]=1[CH3:34])=[O:8]参加物
5
実験手順
1.5 A solution of 4.5 g of 5-bromo-2,4-dibenzyloxybenzoyl chloride in 6 ml of dichloromethane is added dropwise with ice-cooling to a solution of 1.126 ml of o-toluidine and 1.211 ml of pyridine in 40 ml of dichloromethane. The mixture is stirred at room temperature for a further 16 hours and subjected to conventional work-up, giving 3 g of 5-bromo-2,4-dibenzyloxy-N-o-tolylbenzamide.