反応式
[F-:1].[K+].[F:3][S:4]([C:7]([F:12])([F:11])[C:8]([F:10])=[O:9])(=[O:6])=[O:5].[Br:13]Br.[F:15][C:16]([F:20])=[C:17]([F:19])[F:18].S(=O)(O)[O-].[Na+]>ClC(Cl)(F)C(Cl)(F)F.C(#N)C>[F:3][S:4]([C:7]([C:8]([O:9][C:16]([C:17]([Br:13])([F:19])[F:18])([F:20])[F:15])([F:1])[F:10])([F:12])[F:11])(=[O:6])=[O:5]参加物
8
反応条件
- 温度
- 80 °C
実験手順
A mixture of 5.8 g potassium fluoride, 60 ml acetonitrile and 12 ml fluorosulfonyl difluoroacetyl fluoride was heated at 80° C. for one hour. The resulting mixture was placed in a stainless steel autoclave and heated at 50° C. for one hour and 80° C. for one hour with 16 g of bromine and 30 g of tetrafluoroethylene. The reaction mixture was poured into a solution of sodium bisulfite, 50 ml 1,1,2-trichloro-1,2,2-trifluoroethane was added and the mixture was distilled to give a distillate boiling up to 100° C. which contained two layers. The organic layer was separated and distilled to give FSO2CF2CF2OCF2CF2Br, b.p. 106°, confirmed by infrared, nuclear magnetic resonance and mass spectroscopy.
後処理
- additionwas added
- distillationthe mixture was distilled
- customto give a distillate
- customboiling up to 100° C.
- customThe organic layer was separated
- distillationdistilled
出典と根拠
- ORDレコード
- ord-4ff494e2acf84bd7b010e48613ebf165
- 出典データセット
- uspto-grants-1983_11
- 特許番号
- US04414280
関連ノート
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