Benzoic Acid → Phthalic Anhydride

HRID 1658537

反応式

HRID 1658537 の反応式
C(O)(=O)/C=C\C(O)=O.[C:9]([OH:20])(=[O:19])[C:10]1[C:11](=[CH:15][CH:16]=[CH:17][CH:18]=1)[C:12]([OH:14])=O.C(O)(=O)/C(=C\C(O)=O)/C.C(O)(=O)C1C=CC=CC=1>CC1C=CC=CC=1C>[C:12]1(=[O:14])[O:20][C:9](=[O:19])[C:10]2=[CH:18][CH:17]=[CH:16][CH:15]=[C:11]12

参加物

6

反応物 4

HCID 243Benzoic AcidHCID 1017Phthalic AcidHCID 444266Maleic AcidHCID 643798Citraconic acid

生成物 1

HCID 6811Phthalic Anhydride

試薬・触媒・溶媒 1

HCID 7237O-Xylene溶媒

実験手順

3200 parts of a 22% solution of maleic acid which contains 4% of other acids such as phthalic acid, citraconic acid and benzoic acid is supplied per hour through a tubular heater which preheats to 100°C to a falling-film evaporator. This solution has been obtained by scrubbing offgas obtained in the manufacture of phthalic anhydride by catalytic oxidation of o-xylene with air at a temperature of 40°C. In the first evaporator the solution is concentrated at atmospheric pressure and at 120°C to a content of 40% of maleic acid. The aqueous condensate is returned to the offgas scrubber.

後処理

  1. waitis supplied per hour through a tubular heater which
  2. custompreheats to 100°C to a falling-film evaporator
  3. customThis solution has been obtained

出典と根拠

ORDレコード
ord-fb618f9aa40648e2a89ee654d917f6ad
出典データセット
uspto-grants-1976_06
特許番号
US03965126

関連ノート

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