Palladium Chloride → Palladium triflate

HRID 1682776ノート

反応式

HRID 1682776 の反応式
Cl[Pd:2]Cl.[OH:4][S:5]([C:8]([F:11])([F:10])[F:9])(=[O:7])=[O:6]>C(Cl)Cl>[O-:7][S:5]([C:8]([F:11])([F:10])[F:9])(=[O:6])=[O:4].[Pd+2:2].[O-:7][S:5]([C:8]([F:11])([F:10])[F:9])(=[O:6])=[O:4]

参加物

4

反応物 2

HCID 24290Palladium ChlorideHCID 62406Trifluoromethanesulfonic acid

生成物 1

HCID 11603820Palladium triflate

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

PdCl2 (1.0 g, 5.6 mmol) was slurried in CH2Cl2 (20 mL) and triflic acid (1.7 g, 11.3 mmol) was added dropwise. The mixture was stirred at room temperature overnight. The solvent was removed and 0.9 g of rust color solid was collected. 19F NMR (CDCl3): δ-5 78.5.

後処理

  1. customThe solvent was removed
  2. custom0.9 g of rust color solid was collected

出典と根拠

ORDレコード
ord-f53ff08b482544a3899a442bed6f5ef3
出典データセット
uspto-grants-1997_06
特許番号
US05635585

反応ノート

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