Santonox → N-(1-methylethyl)-3-(3-methoxyphenyl)-2-oxiranecarboxamide

HRID 1759521

反応式

HRID 1759521 の反応式
[CH3:1][CH:2]([NH:4][C:5]([C:7](=O)C=CC1C=CC=C(OC)C=1)=[O:6])[CH3:3].Cl[C:20]1[CH:25]=[CH:24][CH:23]=[C:22]([C:26]([O:28]O)=O)[CH:21]=1.S(C1C(C)=CC(O)=C(C(C)(C)C)C=1)C1C(C)=C[C:34]([OH:41])=C(C(C)(C)C)C=1>C(Cl)CCl>[CH3:1][CH:2]([NH:4][C:5]([CH:7]1[CH:26]([C:22]2[CH:23]=[CH:24][CH:25]=[C:20]([O:41][CH3:34])[CH:21]=2)[O:28]1)=[O:6])[CH3:3]

参加物

5

反応物 3

HCID 7308SantonoxHCID 70297m-Chloroperbenzoic acidHCID 54220101N-(1-methylethyl)-3-methoxycinnamoylcarboxamide

生成物 1

HCID 20490547N-(1-methylethyl)-3-(3-methoxyphenyl)-2-oxiranecarboxamide

試薬・触媒・溶媒 1

HCID 111,2-Dichloroethane溶媒

実験手順

This compound was prepared from N-(1-methylethyl)-3-methoxycinnamoylcarboxamide (43.9 g.), m-chloroperbenzoic acid (46 g.), 4,4'-thiobis(6-tert-butyl-m-cresol) (0.6 g.), and ethylene dichloride (500 ml.) as described in Example 7. The compound obtained as an oil was used directly in the subsequent reaction.

後処理

  1. customThe compound obtained as an oil
  2. customwas used directly in the subsequent reaction

出典と根拠

ORDレコード
ord-52273c1409cf476cafcc5281fecb1265
出典データセット
uspto-grants-1982_07
特許番号
US04341718

関連ノート

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