Styrene → 3,3-Dichloro-1,5-diphenyl-3-silahexane
反応式
[C:1]1([CH:7]([CH3:12])[CH2:8][SiH:9]([Cl:11])[Cl:10])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH2:13]=[CH:14][C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1>C(O)(C)C.[H+].[H+].Cl[Pt-2](Cl)(Cl)(Cl)(Cl)Cl>[Cl:10][Si:9]([Cl:11])([CH2:8][CH:7]([C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)[CH3:12])[CH2:13][CH2:14][C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1参加物
5
実験手順
In the same apparatus and procedures as EXAMPLE 1, 10.0 g (0.046 mole) of 3-phenyl-1,1-dichloro-1-silabutane, 7.2 g (0.07 mole) of styrene, and 20 μl of 1% chloroplatinic acid in isopropanol were placed and reacted for 3 hours under the dry nitrogen atmosphere at 60° C. Vacuum distillation of the reaction products gave 11.0 g (bp, 133°-5° C./0.6 mmHg) of 3,3-dichloro-1,5-diphenyl-3-silahexane.