Water → HCID 12257138、化合物

反応式

[CH:1]1[CH2:5][CH2:4][CH2:3][CH:2]=1.[N+]([O-])([O-])=O.[Hg+2:10].[N+]([O-])([O-])=O.[Cl-:15].[Na+].[OH2:17].[C:18](#[N:20])[CH3:19]>>[C:18]([NH:20][C@@H:1]1[CH2:5][CH2:4][CH2:3][C@H:2]1[Hg:10][Cl:15])(=[O:17])[CH3:19]

参加物

反応物 5

HCID 962Water

HCID 5234Sodium Chloride

HCID 6342Acetonitrile2 回

HCID 8882Cyclopentene

HCID 24864Mercuric nitrate

生成物 1

HCID 12257138HCID 12257138、化合物

実験手順

10 ml of cyclopentene in 30 ml of acetonitrile are added dropwise to a suspension of 38.3 g of mercury(II) nitrate in 80 ml of acetonitrile at 0° C. After 1 hour at room temperature, the mixture is poured into a mixture of 60 ml of saturated sodium chloride solution and 250 ml of water, and the solid is filtered off with suction, washed with water and dried. 26 g of the title compound are obtained as an amorphous powder.