4-tert-Butylcyclohexanol → 4-Tert-butylcyclohex-1-ene

HRID 1828330

反応式

HRID 1828330 の反応式
[C:1]([CH:5]1[CH2:10][CH2:9][CH:8](O)[CH2:7][CH2:6]1)([CH3:4])([CH3:3])[CH3:2].OS([O-])(=O)=O.[K+].C(OC(=O)C)C.OS([O-])(=O)=O.[K+]>>[C:1]([CH:5]1[CH2:10][CH2:9][CH:8]=[CH:7][CH2:6]1)([CH3:4])([CH3:3])[CH3:2]

参加物

4

反応物 3

HCID 73914-tert-ButylcyclohexanolHCID 516920Potassium bisulfateHCID 86585043ethylacetate KHSO4

生成物 1

HCID 166884-Tert-butylcyclohex-1-ene

反応条件

温度
95 °C

実験手順

20 g 4-t-butyl-1-cyclohexanol are mixed with 17 g KHSO4 and stirred for one week at 95° C. After the addition of ethylacetate KHSO4 is filtered off. Ethylacetate is evaporated and the product obtained by fractional distillation.

後処理

  1. filtrationis filtered off
  2. customEthylacetate is evaporated
  3. customthe product obtained by fractional distillation

出典と根拠

ORDレコード
ord-af0b71c7642b4961a781a860d53df6c6
出典データセット
uspto-grants-2006_06
特許番号
US07057059B2

関連ノート

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