Cyclopentanone → Cyclopentanol, acetate

HRID 1885056ノート

反応式

HRID 1885056 の反応式
N([O:3][C:4](C)(C)[CH3:5])=O.ON1[C:13](=[O:14])[C:12]2=[CH:15][CH:16]=[CH:17]C=C2C1=O.C1(=NO)CCCC1.[N+](C1CCCC1)([O-])=O.C1(=O)CCCC1>C(O)(=O)C.C1CCCC1>[C:4]([O:14][CH:13]1[CH2:12][CH2:15][CH2:16][CH2:17]1)(=[O:3])[CH3:5]

参加物

8

反応物 5

HCID 8452CyclopentanoneHCID 10665N-HydroxyphthalimideHCID 10906Tert-Butyl nitriteHCID 14500Cyclopentanone, oximeHCID 75714Nitrocyclopentane

生成物 1

HCID 70273Cyclopentanol, acetate

試薬・触媒・溶媒 2

HCID 176Acetic Acid溶媒HCID 9253Cyclopentane溶媒

反応条件

温度
80 °C

実験手順

Cyclopentane (1 ml), t-butyl nitrite (1 mmol), N-hydroxyphthalimide (0.2 mmol), and acetic acid (1 ml) were placed in a flask and were stirred at 80° C. in an atmosphere of argon gas (1 atm=0.101 MPa) for 20 hours. The resulting reaction mixture was analyzed to find that cyclopentanone oxime, nitrocyclopentane, cyclopentanone, and cyclopentyl acetate were formed in yields of 4%, 2%, 3%, and less than 1%, respectively.

後処理

  1. customThe resulting reaction mixture

出典と根拠

ORDレコード
ord-346888ec32b94910b8e7ef670780cedf
出典データセット
uspto-grants-2004_07
特許番号
US06768023B2

反応ノート

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