Perfluorooctyl iodide → Methyl perfluorooctyl sulphide

HRID 1974787

反応式

HRID 1974787 の反応式
[F:1][C:2](I)([F:25])[C:3]([F:24])([F:23])[C:4]([F:22])([F:21])[C:5]([F:20])([F:19])[C:6]([F:18])([F:17])[C:7]([F:16])([F:15])[C:8]([F:14])([F:13])[C:9]([F:12])([F:11])[F:10].S(S([O-])=O)([O-])=O.[Na+].[Na+].P([O-])([O-])(O)=O.[Na+].[Na+].[CH3:42][S:43]SC>CN(C)C=O.O>[F:1][C:2]([S:43][CH3:42])([F:25])[C:3]([F:24])([F:23])[C:4]([F:22])([F:21])[C:5]([F:20])([F:19])[C:6]([F:18])([F:17])[C:7]([F:16])([F:15])[C:8]([F:14])([F:13])[C:9]([F:12])([F:11])[F:10]

参加物

7

反応物 4

HCID 10491Perfluorooctyl iodideHCID 12232Dimethyl DisulfideHCID 24203Sodium Phosphate, DibasicHCID 24489Sodium Dithionite

生成物 1

HCID 10504381Methyl perfluorooctyl sulphide収率 20%

試薬・触媒・溶媒 2

HCID 962Water溶媒HCID 6228Dimethylformamide溶媒

実験手順

Perfluorooctyl iodide (5.5 g), sodium dithionite (3 g), sodium hydrogen phosphate (3 g) and methyl disulphide (1 g) are stirred in dimethylformamide (10 cc) and water (5 cc) for 6 hours. After the usual treatment, methyl perfluorooctyl sulphide is obtained in 20% yield.

出典と根拠

ORDレコード
ord-46b8bcc862df406cb7effd7aa6decbca
出典データセット
uspto-grants-1994_02
特許番号
US05283337

関連ノート

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