Sodium Hydroxide → HCID 13997673、化合物

HRID 1977266

反応式

HRID 1977266 の反応式
C[O:2][C:3](=[O:16])[C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([O:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15])[CH:5]=1.[OH-].[Na+].OCl>CO>[CH2:11]([O:10][C:6]1[CH:5]=[C:4]([CH:9]=[CH:8][CH:7]=1)[C:3]([OH:16])=[O:2])[CH2:12][CH2:13][CH2:14][CH3:15]

参加物

5

反応物 3

HCID 14798Sodium HydroxideHCID 24341Hypochlorous AcidHCID 18342002Methyl 3-(pentyloxy)benzoate

生成物 1

HCID 13997673HCID 13997673、化合物収率 0.1%

試薬・触媒・溶媒 1

HCID 887Methanol溶媒

実験手順

To 3-amyloxybenzoic acid methyl ester (35 g) in methanol (200 ml) was added 1N-sodium hydroxide aqueous solution (200 ml) and the mixture was stirred for 2 days at room temperature. Hydroxy chloride (20 ml) was added to the raction mixture. The precipitate was filtered and washed with water, acetonitrile and diisopropyl ether to give 3-amyloxybenzoic acid (30 mg).

後処理

  1. filtrationThe precipitate was filtered
  2. washwashed with water, acetonitrile and diisopropyl ether

出典と根拠

ORDレコード
ord-eabdd1dd6f314dd5b90acfe550ac6820
出典データセット
uspto-grants-2001_05
特許番号
US06232290B1

関連ノート

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