Phthalic Anhydride → HCID 12961629、化合物

HRID 2058781ノート

反応式

HRID 2058781 の反応式
[C:1]1(=[O:11])[O:6][C:4](=[O:5])[C:3]2=[CH:7][CH:8]=[CH:9][CH:10]=[C:2]12.[CH3:12][N:13]([C:15]1[O:16][C:17]2[CH:23]=[CH:22][CH:21]=[CH:20][C:18]=2[N:19]=1)[NH2:14]>C(Cl)(Cl)Cl>[C:4]([C:3]1[CH:7]=[CH:8][CH:9]=[CH:10][C:2]=1[C:1]([NH:14][N:13]([C:15]1[O:16][C:17]2[CH:23]=[CH:22][CH:21]=[CH:20][C:18]=2[N:19]=1)[CH3:12])=[O:11])([OH:6])=[O:5]

参加物

4

反応物 2

HCID 6811Phthalic AnhydrideHCID 129616282-(1-Methylhydrazino)benzoxazole

生成物 1

HCID 12961629HCID 12961629、化合物

試薬・触媒・溶媒 1

HCID 6212Chloroform溶媒

実験手順

A suspension of 5.2 g. of phthalic anhydride in 75 ml. of chloroform is stirred and treated with 5.7 g. of 2-(1-methylhydrazino)benzoxazole. A clear yellow solution results and the temperature drops several degrees, then rises to 33+ C. After about 15 min. precipitation of a solid begins. An additional 200 ml. of chloroform is added and the mixture is stirred overnight. The solid is filtered, washed with chloroform and dried to give 8.6 g. of product, m.p. 140°-142°.

後処理

  1. additionA suspension of 5.2 g
  2. additiontreated with 5.7 g
  3. customA clear yellow solution results
  4. customAfter about 15 min. precipitation of a solid
  5. additionof chloroform is added
  6. filtrationThe solid is filtered
  7. washwashed with chloroform
  8. customdried
  9. customto give 8.6 g

出典と根拠

ORDレコード
ord-03c547f0df514eb9aad55ba142266606
出典データセット
uspto-grants-1982_03
特許番号
US04319026

反応ノート

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