Acetic Acid → HCID 75985013、化合物
反応式
Br[CH2:2][C:3]([O:11][CH3:12])=[CH:4][C:5](=[O:10])[C:6]([Cl:9])([Cl:8])[Cl:7].[C:13]([O-:16])(=[O:15])[CH3:14].[K+].C(O)(=O)C>[Br-].C([N+](CCCC)(CCCC)CCCC)CCC.C(#N)C>[C:13]([O:16][CH2:2][C:3]([O:11][CH3:12])=[CH:4][C:5](=[O:10])[C:6]([Cl:9])([Cl:8])[Cl:7])(=[O:15])[CH3:14]参加物
6
実験手順
29.6 g (0.1 mol) of 5-bromo-1,1,1-trichloro-4-methoxypent-3-en-2-one, 17 g of potassium acetate, 5 g of tetrabutylammonium bromide and 8 g of acetic acid were stirred at 40° C. in 300 ml of acetonitrile for 16 h. The mixture was concentrated under reduced pressure, and the water was added to the residue. The product was extracted with ethyl acetate, the organic phase was washed with water and the solvent was removed completely under reduced pressure.
後処理
- concentrationThe mixture was concentrated under reduced pressure
- additionthe water was added to the residue
- extractionThe product was extracted with ethyl acetate
- washthe organic phase was washed with water
- customthe solvent was removed completely under reduced pressure
出典と根拠
- ORDレコード
- ord-d4988016eb784893b02484463198a10d
- 出典データセット
- uspto-grants-2012_10
- 特許番号
- US08299260B2
反応ノート
読み込み中…