Ammonia → HCID 3046207、化合物
反応式
[NH2-:1].[Na+].N.[Na].[CH2:5]([C:8]([CH2:12][CH2:13][CH3:14])(Cl)[C:9]#[CH:10])[CH2:6][CH3:7]>C(OCC)C>[CH2:5]([C:8]([NH2:1])([CH2:12][CH2:13][CH3:14])[C:9]#[CH:10])[CH2:6][CH3:7]参加物
6
実験手順
To a suspension of sodium amide in liquid ammonia, prepared from 6.9 g of sodium and 250 ml of liquid ammonia, were added 17 g of 1,1-di-n-propyl-1-chloro-2-propyne in 50 ml of anhydrous ethyl ether. The operation of adding the chlorinated derivative lasted one hour. Stirring of the mixture was maintained for 2 hours and then 300 ml of anhydrous ethyl ether were added.
後処理
- additionThe operation of adding the chlorinated derivative
- temperaturewas maintained for 2 hours
出典と根拠
- ORDレコード
- ord-109a543cf97045ff8bd490f23c8f1552
- 出典データセット
- uspto-grants-1977_09
- 特許番号
- US04048334
反応ノート
読み込み中…