Pyridine → 9,10-Anthracenedione, 1,5-bis(octadecylamino)-

HRID 2072278ノート

反応式

HRID 2072278 の反応式
Cl[C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[C:9](Cl)[CH:10]=[CH:11][CH:12]=3)[C:7](=[O:18])[C:6]=2[CH:5]=[CH:4][CH:3]=1.[CH2:19]([NH2:37])[CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH3:36].[C:38]([O-])(=O)[CH3:39].[Na+].[N:43]1[CH:48]=[CH:47][CH:46]=[CH:45][CH:44]=1>C1C=CC=CC=1.C([O-])(=O)C.[Cu+2].C([O-])(=O)C>[CH2:19]([NH:37][C:2]1[C:15]2[C:14](=[O:16])[C:13]3[C:8](=[C:9]([NH:43][CH2:48][CH2:47][CH2:46][CH2:45][CH2:44][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH2:15][CH2:14][CH2:38][CH3:39])[CH:10]=[CH:11][CH:12]=3)[C:7](=[O:18])[C:6]=2[CH:5]=[CH:4][CH:3]=1)[CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH3:36]

参加物

7

反応物 4

HCID 1049PyridineHCID 67111,5-DichloroanthraquinoneHCID 15793OctadecylamineHCID 517045Sodium Acetate

生成物 1

HCID 30980749,10-Anthracenedione, 1,5-bis(octadecylamino)-

試薬・触媒・溶媒 2

HCID 8895Cupric acetate触媒HCID 241Benzene溶媒

実験手順

A reactor was charged with 1.4 g of 1, 5-dichloroanthraquinone, 33.6 g. of stearyl amine, 1.3 g of sodium acetate, 0.3 g of copper acetate and 3.2 g of pyridine and the reaction was effected at 80° C. for 15 hours under stirring. The resulting red solid was dissolved in benzene and insoluble matters were removed, followed by distillation of benzene and recystallization from glacial acetic acid. Thus 1, 5-di-n-octadecylaminoanthraquinone was obtained by the reaction of the following formula: ##STR7## Preparation of Liquid Developer:

後処理

  1. custominsoluble matters were removed
  2. distillationfollowed by distillation of benzene and recystallization from glacial acetic acid

出典と根拠

ORDレコード
ord-a0feefa5c5314e0fa83208be9fb5c82c
出典データセット
uspto-grants-1977_09
特許番号
US04051052

反応ノート

読み込み中…