4-(Octyloxy)benzoic acid → 4-Octyloxybenzoyl chloride

反応式

[CH2:1]([O:9][C:10]1[CH:18]=[CH:17][C:13]([C:14](O)=[O:15])=[CH:12][CH:11]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].S(Cl)([Cl:21])=O>>[CH2:1]([O:9][C:10]1[CH:18]=[CH:17][C:13]([C:14]([Cl:21])=[O:15])=[CH:12][CH:11]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

参加物

反応物 2

HCID 172314-(Octyloxy)benzoic acid

HCID 24386Thionyl Chloride

生成物 1

HCID 27602504-Octyloxybenzoyl chloride

実験手順

After 4-n-octyloxybenzoic acid (11 g) and an excessive amount of thionyl chloride were heated under refluxing for 6 hours, unaltered thionyl chloride was distilled off to obtain 4-n-octyloxybenzoic acid chloride.

後処理

temperatureunder refluxing for 6 hours
distillationunaltered thionyl chloride was distilled off

出典と根拠

ORDレコード: ord-5b3123598dd24b67aaa81a9b9a420d75
出典データセット: uspto-grants-1995_06
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US05424005

反応ノート

読み込み中…