Acetic Anhydride → Citronellyl Acetate

HRID 2164189

反応式

HRID 2164189 の反応式
[CH3:1][CH:2]([CH2:6][CH2:7][CH:8]=[C:9]([CH3:11])[CH3:10])[CH2:3][CH2:4][OH:5].[C:12](OC(=O)C)(=[O:14])[CH3:13]>N1C=CC=CC=1>[C:12]([O:5][CH2:4][CH2:3][CH:2]([CH3:1])[CH2:6][CH2:7][CH:8]=[C:9]([CH3:10])[CH3:11])(=[O:14])[CH3:13]

参加物

4

反応物 2

HCID 7918Acetic AnhydrideHCID 8842Citronellol

生成物 1

HCID 9017Citronellyl Acetate

試薬・触媒・溶媒 1

HCID 1049Pyridine溶媒

実験手順

100 Grams of 3,7-dimethyloct-6-en-1-ol is dissolved in 150 ml. of pyridine and 100 ml. of acetic anhydride and left at room temperature for about 48 hours. Then the mixture is extracted with ether and the ethereal extracts washed with water, 10% aqueous HCl and brine to yield 1-acetoxy-3,7-dimethyloct-6-ene which is purified by distillation.

後処理

  1. extractionThen the mixture is extracted with ether
  2. washthe ethereal extracts washed with water, 10% aqueous HCl and brine

出典と根拠

ORDレコード
ord-bd39ca3e5fdc410baafd6f53f8e929f7
出典データセット
uspto-grants-1979_01
特許番号
US04137273

関連ノート

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