Menthyl Anthranilate → 4-Aminobenzoic Acid

反応式

[NH2:1][C:2]1[CH:15]=[CH:14][C:5]([C:6]([O:8]CC(O)CO)=[O:7])=[CH:4][CH:3]=1.C(N(C1C=CC(C(O)=O)=C(CCCCCCC(=O)C2C=CC=CC=2)C=1O)CC)C.C(N(CC)C1C=CC(C(C2C=CC=CC=2C(OCCCCCC)=O)=O)=C(O)C=1)C.NC1C=CC=CC=1C(OC1CC(C)CCC1C(C)C)=O>>[NH2:1][C:2]1[CH:15]=[CH:14][C:5]([C:6]([OH:8])=[O:7])=[CH:4][CH:3]=1

参加物

反応物 3

HCID 8633Menthyl Anthranilate

HCID 86922,3-Dihydroxypropyl 4-aminobenzoate

HCID 86702319Hexyl 2-[4-(diethylamino)-2-hydroxybenzoyl]benzoate (diethylamino hydroxy benzoyl hexylbenzoate)

生成物 1

HCID 9784-Aminobenzoic Acid

実験手順

digalloyl triolate; 2,3-dihydroxypropyl 4-aminobenzoate (lisadimate, amyl dimethyl PABA, glyceryl PABA); ethyl-4-bis(hydroxypropyl)-aminobenzoate (roxadimate); ethoxylated ethyl 4-aminobenzoate (PEG-25 PABA); hexyl 2-[4-(diethylamino)-2-hydroxybenzoyl]benzoate (diethylamino hydroxy benzoyl hexylbenzoate); (5-methyl-2-propan-2-ylcyclohexyl) 2-aminobenzoate (menthyl anthranilate, meradimate);

出典と根拠

ORDレコード: ord-856c093d2e4b469a9dc95f405e1422da
出典データセット: uspto-grants-2015_06
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US09044623B2

反応ノート

読み込み中…

参加物