Adipic Acid → Sodium silicate butadiene propylene oxide

HRID 223428

反応式

HRID 223428 の反応式
[Si:1]([O-:5])([O-:4])([O-:3])[O-:2].[Na+:6].[Na+].[Na+].[Na+].[C:10](O)(=O)[CH2:11][CH2:12][CH2:13]CC(O)=O.C=CC=C.[CH2:24]1[O:27][CH:25]1[CH3:26].[Na].OO.C(S)CCCCCCCCCCC>>[Si:1]([O-:5])([O-:4])([O-:3])[O-:2].[Na+:6].[Na+:6].[Na+:6].[Na+:6].[CH2:10]=[CH:11][CH:12]=[CH2:13].[CH2:24]1[O:27][CH:25]1[CH3:26]

参加物

8

反応物 7

HCID 196Adipic AcidHCID 784Hydrogen PeroxideHCID 6378Propylene OxideHCID 78451,3-ButadieneHCID 81951-DodecanethiolHCID 26051Sodium orthosilicateHCID 5360545Sodium

生成物 1

HCID 86738392Sodium silicate butadiene propylene oxide

実験手順

About 50 parts by weight of an aqueous sodium silicate solution containing about 10% Na2O and 15% SiO2, 1 part by weight of adipic acid, 20 parts by weight of butadiene, 5 parts by weight of propylene oxide, 0.5 parts by weight of sodium salt of fatty acids, 0.05 to 0.1 parts by weight of ferric sulfate, 0.1 parts by weight of hydrogen peroxide, 0.01 parts by weight of benzoxyl peroxide and 0.1 parts by weight of lauryl mercaptan are mixed in a closed system at ambient to 50° C. while agitating at about 0.40 to 6 psiq for 30 to 120 minutes; then the mixture is heated to 70° to 100° C. at ambient pressure for 10 to 30 minutes. The reaction is complete within 24 hours thereby producing an emulsion of poly(sodium silicate-butadiene-propylene oxide) copolymer.

後処理

  1. additionare mixed in a closed system at ambient to 50° C.
  2. temperaturethen the mixture is heated to 70° to 100° C. at ambient pressure for 10 to 30 minutes
  3. waitThe reaction is complete within 24 hours

出典と根拠

ORDレコード
ord-42e532452d754a9ea9b0fb803ef4e65d
出典データセット
uspto-grants-1982_10
特許番号
US04353999

関連ノート

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