Hydrochloric Acid → HCID 54254998、化合物

HRID 223649

反応式

HRID 223649 の反応式
[CH3:1][C:2]1([CH3:17])[CH2:13][CH:12]=[CH:11][CH2:10][CH2:9][CH:8]=[CH:7][CH2:6][CH:5]([CH:14]([CH3:16])[CH3:15])[N:4]=[CH:3]1.Cl.Cl.[NH2:20][NH:21][C:22]([NH2:24])=[O:23]>O>[CH3:1][C:2]([CH3:17])([CH2:13][CH:12]=[CH:11][CH2:10][CH2:9][CH:8]=[CH:7][CH2:6][CH:5]([CH:14]([CH3:16])[CH3:15])[NH2:4])[CH:3]=[N:20][NH:21][C:22]([NH2:24])=[O:23]

参加物

5

反応物 3

HCID 313Hydrochloric AcidHCID 11236Semicarbazide hydrochlorideHCID 5575123,3-Dimethyl-12-isopropyl-1-aza-1,5,9-cyclododecatriene

生成物 1

HCID 54254998HCID 54254998、化合物収率 86%

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

The procedure described in Example 1(b) is repeated, except that 23.3 g (0.1 mol) of 3,3-dimethyl-12-isopropyl-1-aza-1,5,9-cyclododecatriene, 20 g of 37% hydrochloric acid, 20 ml of water and 11.15 g (0.1 mol) of semicarbazide hydrochloride are used. Working up yields 26.5 g (0.086 mol) of 2,2-dimethyl-11-isopropyl-11-amino-undeca-4,8-dienal semicarbazone; yield 86% of theory.

出典と根拠

ORDレコード
ord-9aa670777b5f407bba7fb02256f2d00a
出典データセット
uspto-grants-1982_10
特許番号
US04355177

関連ノート

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