反応式
[CH3:1][C:2](=[CH2:4])[CH3:3].C=CCC.S(=O)(=O)(O)O.O.[C:15](O)([CH3:18])([CH3:17])[CH3:16]>>[CH3:4][C:2]([CH2:3][C:15]([CH3:18])([CH3:17])[CH3:16])=[CH2:1].[CH3:3][C:2](=[CH2:1])[CH3:4]参加物
7
反応条件
- 温度
- 60 °C
実験手順
Into a 300 ml pressure-resistant glass autoclave were charged 10 g of isobutylene, 10 g of 1-butene, 50 g of sulfuric acid and 50 g of water, and the mixture was stirred at 60° C. at a pressure of 8.5 atms for one hour. As a result, isobutylene was hydrated to form tert-butanol with the conversion of 90% and the selectivity to tert-butanol of 92%. At the same time, diisobutylene and the trimer of isobutylene were produced at a yield of 2% and 6%, respectively, and 1-butene was hydrated to form sec-butanol at a yield of 4%.
出典と根拠
- ORDレコード
- ord-40f12d48f3494f3a8abc6c09cfb540f6
- 出典データセット
- uspto-grants-1980_11
- 特許番号
- US04236034
関連ノート
読み込み中…