Ethylene Glycol → 2-[2-[2-(2-Chloroethoxy)ethoxy]ethoxy]ethanol

HRID 2254013

反応式

HRID 2254013 の反応式
Cl[CH2:2][CH2:3][O:4][CH2:5][CH2:6][O:7][CH2:8][CH2:9][Cl:10].[OH-].[K+].[CH2:13]([OH:16])[CH2:14][OH:15]>>[Cl:10][CH2:9][CH2:8][O:7][CH2:6][CH2:5][O:4][CH2:3][CH2:2][O:15][CH2:14][CH2:13][OH:16]

参加物

4

反応物 3

HCID 174Ethylene GlycolHCID 81711,2-Bis(2-chloroethoxy)ethaneHCID 14797Potassium Hydroxide

生成物 1

HCID 1384342-[2-[2-(2-Chloroethoxy)ethoxy]ethoxy]ethanol収率 30%

実験手順

A solution of 1,8-dichloro-3,6-dioxaoctane (40 g) and potassium hydroxide (11.8 g) in ethylene glycol (100 ml) was stirred at 100° C. for 18 h. The mixture was then cooled, filtered and the residue washed with acetone (2×35 ml). The combined filtrate was then distilled to yield the product as a clear oil (13.5 g, 30%), b.p. 120°-122° C./0.2 mm Hg; I.r. (liquid film) 3430 cm-1.

後処理

  1. temperatureThe mixture was then cooled
  2. filtrationfiltered
  3. washthe residue washed with acetone (2×35 ml)
  4. distillationThe combined filtrate was then distilled

出典と根拠

ORDレコード
ord-de91fa38117e4819b849dd7164a85e16
出典データセット
uspto-grants-1993_08
特許番号
US05234566

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