Diethylaluminum chloride → 1-Octene

HRID 22578

反応式

HRID 22578 の反応式
[Al](Cl)([CH2:4][CH3:5])[CH2:2]C.[H][H].[CH3:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15]>>[CH2:9]=[CH:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:4][CH3:5].[CH2:9]=[CH:10][CH2:11][CH2:12][CH2:13][CH2:14][CH:15]=[CH2:2]

参加物

5

反応物 3

HCID 7277Diethylaluminum chlorideHCID 8900HeptaneHCID 178418361HCID 178418361、化合物

生成物 2

HCID 81251-OcteneHCID 194601,7-Octadiene

実験手順

A solution of 106.4 grams (0.95 mole) 1-octene and 5.5 grams (0.0509 mole) 1,7-octadiene (molar charge ratio 95:5) in 450 grams of heptane was polymerized with Et2AlCl (16 millimoles) and AATiCl3 (4.0 millimoles) at 50° C. for 10 hours. During the course of the reaction, hydrogen was bubbled through the reaction mixture. The conversion of the polymer was 65 percent, inherent viscosity was 2.1 dl/gram. The composition of monomers in the copolymer was 97:3 mole ratio from NMR analysis.

後処理

  1. customwas bubbled through the reaction mixture

出典と根拠

ORDレコード
ord-058afdbfbf544fed8cd88265b6b3e285
出典データセット
uspto-grants-1995_06
特許番号
US05428209

関連ノート

読み込み中…