Styrene → (2-Phenylethyl)trichlorosilane

HRID 2268197

反応式

HRID 2268197 の反応式
[CH2:1]=[CH:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[Cl:9][SiH:10]([Cl:12])[Cl:11]>[Pt].C1(C)C=CC=CC=1>[CH2:1]([Si:10]([Cl:12])([Cl:11])[Cl:9])[CH2:2][C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

参加物

5

反応物 2

HCID 7501Styrene3 回HCID 24811Trichlorosilane2 回

生成物 1

HCID 70327(2-Phenylethyl)trichlorosilane収率 39%

試薬・触媒・溶媒 2

HCID 23939Platinum触媒HCID 1140Toluene溶媒

実験手順

Reaction between styrene and trichlorosilane with platinum catalyst (no substance acting as auxiliary catalyst). 518 mg Styrene and 694 mg trichlorosilane were introduced into a glass tube, and 2.5 mg of a toluene solution of a 0-valent platinum complex of divinylsiloxane (0.04 wt % platinum content) were added. The tube was sealed with Teflon tape and a rubber septum and then placed in a 50° C. oil bath where it was heated for 30 minutes. After cooling, the tube contents were analyzed by gas chromatography revealing a styrene conversion of 93% and a phenethyltrichlorosilane yield of 39%. The ratio between the phenethyltrichlorosilane and the (α-methylbenzyl)trichlorosilane was 5.5:1.

後処理

  1. customplaced in a 50° C.
  2. temperaturewas heated for 30 minutes
  3. temperatureAfter cooling

出典と根拠

ORDレコード
ord-dfa7f6041ba543a6b0f771ff6f6871ed
出典データセット
uspto-grants-2001_12
特許番号
US06326506B1

関連ノート

読み込み中…