Chlorotrimethylsilane → N,N-bis(trimethylsilyl)perfluorooctaneamide

HRID 227365

反応式

HRID 227365 の反応式
[F:1][C:2]([F:25])([C:6]([F:24])([F:23])[C:7]([F:22])([F:21])[C:8]([F:20])([F:19])[C:9]([F:18])([F:17])[C:10]([F:16])([F:15])[C:11]([F:14])([F:13])[F:12])[C:3]([NH2:5])=[O:4].[CH3:26][Si:27]([CH3:30])([CH3:29])Cl.CCCCCCCCCCCCCCCC>CCCCCC>[CH3:26][Si:27]([CH3:30])([CH3:29])[N:5]([Si:27]([CH3:30])([CH3:29])[CH3:26])[C:3](=[O:4])[C:2]([F:25])([F:1])[C:6]([F:23])([F:24])[C:7]([F:21])([F:22])[C:8]([F:19])([F:20])[C:9]([F:17])([F:18])[C:10]([F:15])([F:16])[C:11]([F:14])([F:13])[F:12]

参加物

5

反応物 3

HCID 6397ChlorotrimethylsilaneHCID 11006HexadecaneHCID 679192,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Pentadecafluorooctanamide

生成物 1

HCID 86615112N,N-bis(trimethylsilyl)perfluorooctaneamide

試薬・触媒・溶媒 1

HCID 8058Hexane溶媒

実験手順

First, perfluorooctaneamide (CF3(CF2)7CONH2) (46 g) was dissolved in n-hexane (300 ml). Thereafter, trimethylchlorosilane (15 ml) was dropped gradually into the solution obtained above, in a dry nitrogen atmosphere. Then this was allowed to react for two hours while being stirred. After the reaction was completed, hexadecane contained in the reaction solution was removed with the evaporator. Thus, N,N-bis(trimethylsilyl)perfluorooctaneamide was obtained.

後処理

  1. customobtained above, in a dry nitrogen atmosphere
  2. customto react for two hours
  3. customwas removed with the evaporator

出典と根拠

ORDレコード
ord-297020bd8b424536ad1a50bc562a8510
出典データセット
uspto-grants-2009_07
特許番号
US07560301B2

関連ノート

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