Chloroethane → Ethane

HRID 2290179ノート

反応式

HRID 2290179 の反応式
[Mg:1].[CH2:2](Cl)[CH3:3].[CH2:5](Cl)[CH2:6][CH2:7][CH3:8]>CCCCCCC>[CH2:5]([Mg:1][CH2:2][CH3:3])[CH2:6][CH2:7][CH3:8].[CH3:5][CH2:6][CH2:7][CH3:8].[CH3:2][CH3:3]

参加物

7

反応物 3

HCID 6337ChloroethaneHCID 8005Butyl ChlorideHCID 5462224Magnesium

生成物 3

HCID 6324EthaneHCID 7843ButaneHCID 178448194HCID 178448194、化合物

試薬・触媒・溶媒 1

HCID 8900Heptane溶媒

反応条件

温度
110 °C

実験手順

A ten weight percent (10 wt. %) solution of n-butylethylmagnesium (BEM) in n-heptane was prepared as follows. A pressure bottle was prepared and heated in an oil bath thermostatically controlled at 115° C. The pressure bottle was equipped with a stirrer. Magnesium powder (18.0 grams, 0.0740 mole) was charged to the pressure bottle and allowed to heat at about 110° C. under a purge of nitrogen. The bottle was removed from the bath and 200 grams (g) dry n-heptane was added. A small amount (0.2 g) of triethylaluminum was injected into the heptane under nitrogen atmosphere to serve as an activator and viscosity reducer. After the pressure bottle was established as the bath temperature, a mixture of ethyl chloride (23.9 g, 0.370 mole) and n-butyl chloride (34.2 g, 0.369 mole) was slowly charged. Temperature was held at 115°-120° C. The addition took 1.5 hours; the pressure rose to about 35 psig. Some 30 minutes was allowed for completion of the reaction, and the slurry was allowed to settle while cooling. Analysis of the clear liquid gave the following results: Mg, 2.82 wt. %; Al, 0.02 wt. %; Cl, 0.11 wt. %. Analysis of the hydrolysis gas gave a composition of 50.9 mole percent n-butane and 49.1 mole % ethane.

後処理

  1. customA pressure bottle was prepared
  2. temperatureheated in an oil bath
  3. customthermostatically controlled at 115° C
  4. customThe pressure bottle was equipped with a stirrer
  5. customa purge of nitrogen
  6. customThe bottle was removed from the bath and 200 grams (g) dry n-heptane
  7. additionwas added
  8. additionwas slowly charged
  9. customwas held at 115°-120° C
  10. additionThe addition
  11. customSome 30 minutes was allowed for completion of the reaction
  12. temperaturewhile cooling
  13. customAnalysis of the clear liquid gave the
  14. customfollowing results
  15. customAnalysis of the hydrolysis gas

出典と根拠

ORDレコード
ord-27c2d70193fd4a14882b5c85b4a67a1e
出典データセット
uspto-grants-1986_10
特許番号
US04615843

反応ノート

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