1-Chloro-4-nitrobenzene → HCID 972080、化合物

HRID 2292259ノート

反応式

HRID 2292259 の反応式
Cl[C:2]1[CH:7]=[CH:6][C:5]([N+:8]([O-:10])=[O:9])=[CH:4][CH:3]=1.[F:11][C:12]1[CH:13]=[C:14]([OH:18])[CH:15]=[CH:16][CH:17]=1.[H-].[Na+]>O1CCCC1>[N+:8]([C:5]1[CH:6]=[CH:7][C:2]([O:18][C:14]2[CH:13]=[C:12]([F:11])[CH:17]=[CH:16][CH:15]=2)=[CH:3][CH:4]=1)([O-:10])=[O:9]

参加物

5

反応物 3

HCID 74741-Chloro-4-nitrobenzeneHCID 97433-FluorophenolHCID 24758Sodium hydride

生成物 1

HCID 972080HCID 972080、化合物

試薬・触媒・溶媒 1

HCID 8028Tetrahydrofuran溶媒

実験手順

p-chloro-nitrobenzene and m-fluoro-phenol in tetra-hydrofuran in the presence of sodium hydride were reacted to obtain 3-(4-nitrophenoxy)-fluorobenzene which was nitrated to form 4-nitro-3-(4-nitrophenoxy)-fluorobenzene which was reacted as in Example 1 to obtain 0-[4-nitro-3-(4-nitrophenoxy)-phenyl]-hydroxylamine melting at 132° C.

出典と根拠

ORDレコード
ord-da9608ccfeec422cb9ba9bf864201480
出典データセット
uspto-grants-1989_01
特許番号
US04801717

反応ノート

読み込み中…