Acenaphthylene → 1-Methylthioacenaphthylene
反応式
[CH3:1][S:2]SC.[CH:5]1[C:15]2=[C:16]3[C:11](=[CH:12][CH:13]=[CH:14]2)[CH:10]=[CH:9][CH:8]=[C:7]3[CH:6]=1>N1C=CC=CC=1>[CH3:1][S:2][C:6]1[C:7]2=[C:16]3[C:11](=[CH:10][CH:9]=[CH:8]2)[CH:12]=[CH:13][CH:14]=[C:15]3[CH:5]=1参加物
4
実験手順
As an example of the benefits that can be realized by use of the two-step procedure, controlled potential electrolysis of dimethyl disulfide in the presence of acenaphthylene in the absence of an organic nucleophilic base resulted in copious polymer formation. But when the same electrolysis procedure was conducted in the additional presence of pyridine, an oxidation-resistant adduct of this invention formed which on eliminative aromatization in the second step resulted in the production of 1-methylthioacenaphthylene in 76% yield using electrochemical reductive elimination.
後処理
- customresulted in copious polymer formation
- customan oxidation-resistant adduct of this invention formed which on eliminative aromatization in the second step
出典と根拠
- ORDレコード
- ord-a1736e7a654148eb9171388fc5a46d30
- 出典データセット
- uspto-grants-2002_08
- 特許番号
- US06432294B1
反応ノート
読み込み中…