Methanol → 9,10-Dihydroanthracene
反応式
[CH:1]1[C:14]2[C:5](=[CH:6][C:7]3[C:12]([CH:13]=2)=[CH:11][CH:10]=[CH:9][CH:8]=3)[CH:4]=[CH:3][CH:2]=1.[Ce].CO>COCCOC>[CH:4]1[C:5]2[CH2:6][C:7]3[C:12](=[CH:11][CH:10]=[CH:9][CH:8]=3)[CH2:13][C:14]=2[CH:1]=[CH:2][CH:3]=1参加物
5
実験手順
1.14 mmole of anthracene is reacted with 4.57 m atoms of cerium as powder in 7.5 ml of DME in the conditions of example 9 with application of ultrasound, thus producing anthracenecerium. After action of a methanol excess and the usual treatment, 9,10-dihydroanthracene was isolated with a yield of 59%.
後処理
- customthus producing anthracenecerium
出典と根拠
- ORDレコード
- ord-4d94dcbf8d314500877ef0fa80aacbef
- 出典データセット
- uspto-grants-1989_07
- 特許番号
- US04845201
反応ノート
読み込み中…