Dimethylformamide → Caprylic Acid Phytyl Ester
反応式
[CH3:1][CH:2]([CH2:4][CH2:5][CH2:6][C@H:7]([CH2:9][CH2:10][CH2:11][C@H:12]([CH2:14][CH2:15][CH2:16]/[C:17](=[CH:19]/[CH2:20][OH:21])/[CH3:18])[CH3:13])[CH3:8])[CH3:3].CN(C)C=O.[C:27](Cl)(=[O:35])[CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34]>C1(C)C=CC=CC=1>[CH2:20]([O:21][C:27](=[O:35])[CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34])/[CH:19]=[C:17](/[CH2:16][CH2:15][CH2:14][C@@H:12]([CH2:11][CH2:10][CH2:9][C@@H:7]([CH2:6][CH2:5][CH2:4][CH:2]([CH3:1])[CH3:3])[CH3:8])[CH3:13])\[CH3:18]参加物
5
実験手順
To a solution of 3 g phytol (3,7,11,15-Tetramethyl-2-hexadecen-1-ol), 1,5 g dimethyl formamide in 50 ml toluene is being added dropwise during one half hour a solution consisting of 2 g caprylic acid chloride (excess) in 25 ml toluene at 20° C.