Acrylic Acid → Sodium acrylate sodium acrylamidomethylpropanesulfonate

HRID 234774

反応式

HRID 234774 の反応式
[C:1]([OH:5])(=[O:4])[CH:2]=[CH2:3].[C:6]([NH:10][CH2:11][O:12][S:13]([CH2:16][CH2:17][CH3:18])(=[O:15])=[O:14])(=[O:9])[CH:7]=[CH2:8].[Na:19].S(OOS([O-])(=O)=O)([O-])(=O)=O.[K+].[K+].C(OCCOCC1OC1)C1OC1.[OH-].[Na+:45]>O>[C:1]([O-:5])(=[O:4])[CH:2]=[CH2:3].[Na+:45].[C:6]([NH:10][CH2:11][O:12][S:13]([CH2:16][CH2:17][CH3:18])(=[O:15])=[O:14])(=[O:9])[CH:7]=[CH2:8].[Na:19]

参加物

7

反応物 5

HCID 6581Acrylic AcidHCID 14798Sodium HydroxideHCID 16683Glycol diglycidyl etherHCID 24412Potassium PersulfateHCID 86750231CID 86750231

生成物 1

HCID 86750230Sodium acrylate sodium acrylamidomethylpropanesulfonate

試薬・触媒・溶媒 1

HCID 962Water溶媒

実験手順

51.1 g of acrylic acid was diluted with 22.6 g of water and neutralized with 75.0 g of a 30 wt. % aqueous sodium hydroxide solution under cooling. Thereafter, 143.3 of a 40 wt. % aqueous sodium acrylamidomethylpropanesulfonate solution was added thereto, and then 7.9 g of a 5.2 wt. % aqueous potassium persulfate solution and 0.082 g of epoxy bifunctional cross linking agent (ethylene glycol diglycidyl ether) were added thereto to prepare a homogeneous solution as the aqueous monomer/initiator solution. Thereafter, the same procedure as that of Example 18 was repeated, thereby providing 131.5 g of a sodium acrylate/sodium acrylamidomethylpropanesulfonate copolymer. The resultant polymer was in the form of distorted granular particles having an average diameter of 580 μm and a bulk density of 0.44 g/ml. The measurement was conducted on the resultant polymer particles in the same manner as that of Example 4. The results are given in Table 2.

後処理

  1. temperatureunder cooling
  2. additionwere added
  3. customto prepare a homogeneous solution as the aqueous monomer/initiator solution

出典と根拠

ORDレコード
ord-986895c7ec954b40895eaa075305c3c3
出典データセット
uspto-grants-1997_01
特許番号
US05596056

関連ノート

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