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Formaldehyde → (Z)-3-(2-Bromo-6,11-dihydrodibenz[b,e]oxepin-11-ylidene)-N,N-dimethylpropylamine

HRID 2351116
ノート
印刷プレビュー

反応式

HRID 2351116 の反応式
Br.[Br-].[CH3:3][N:4]([CH3:27])[CH2:5][CH2:6][CH2:7][P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.C([Li])CCC.[Br:33][C:34]1[CH:49]=[CH:48][C:37]2[O:38][CH2:39][C:40]3[CH:47]=[CH:46][CH:45]=[CH:44][C:41]=3[C:42](=O)[C:36]=2[CH:35]=1.C=O>O1CCCC1.CCCCCC.CS(C)=O>[Br:33][C:34]1[CH:49]=[CH:48][C:37]2[O:38][CH2:39][C:40]3[CH:47]=[CH:46][CH:45]=[CH:44][C:41]=3/[C:42](=[CH:7]/[CH2:6][CH2:5][N:4]([CH3:27])[CH3:3])/[C:36]=2[CH:35]=1
参加物実験手順後処理出典と根拠反応ノート

参加物

8

反応物 4

HCID 712Formaldehyde2 回HCID 129291312-Bromo-6H-dibenz[b,e]oxepin-11-oneHCID 23651404(3-(Dimethylamino)propyl)triphenylphosphonium bromide hydrobromideHCID 178418339Butyllithium

生成物 1

HCID 67782130(Z)-3-(2-Bromo-6,11-dihydrodibenz[b,e]oxepin-11-ylidene)-N,N-dimethylpropylamine

試薬・触媒・溶媒 3

HCID 679
Dimethyl Sulfoxide
溶媒
3 回
HCID 8028Tetrahydrofuran溶媒2 回
HCID 8058Hexane溶媒

実験手順

Anhydrous 3-(dimethylamino)propyltriphenylphosphonium bromide hydrobromide (39.4 g., 0.08 mole) was suspended in 450 mL of dry tetrahydrofuran and 100 mL of a solution of n-butyl lithium in hexane (1.6M) was added dropwise at 0° C. under a nitrogen atmosphere during a 30 minute period. After an additional 10 minutes, 2-bromo-6,11-dihydrodibenz[b,e]oxepin-11-one (16.8 g., 0.06 mole) in 150 mL dry tetrahydrofuran was added slowly to the deep red solution and the reaction mixture was then refluxed for 18 hours. The reaction mixture was poured onto ice-water, and the mixture was extracted with diethyl ether. The ether layer was concentrated under reduced pressure and the residue was suspended in water and then acidified with 6N hydrochloric acid. The acidic aqueous layer was washed with hexanes and then was concentrated to give a gummy residue. The residue was crystallized from ethyl acetate/methanol to provide 5.3 g. of pure Z-isomer as its hydrochloride salt, m.p. 201°-204° C. The mother liquor was chromatographed on a silica gel column (Waters Associates-Prep. 500) with ethyl acetate/methanol (8:2) to give an additional 2.55 g. of pure Z-isomer as the hydrochloride salt and 2.79 g. of E-isomer as its hydrochloride salt, m.p. 230°-233° C. pmr (Z-isomer) (DMSO/d6) δ: 7.25-7.44 (m, 6H, aromatic), 6.81 (degenerate d, J=9.1 Hz, 1H, H4), 5.72 (t, J=7.1 Hz, 1H, CH=), 5.22 (s, 2H, CH2O), 3.18 (m, 2H, NCH2), 2.70 (m, 2H, CH2), 2.66 (s, 6H, NMe2). pmr (E-isomer) (DMSO/d6) δ: 7.23-7.50 (m, 6H, aromatic), 6.70 (d, J=8.6 Hz, 1H, H4), 6.10 (t, J=7.2 Hz, 1H, CH=) 5.15 (br s, 2H, CH2O), 3.07 (m, 2H, NCH2), 2.65 (s, 6H, NMe2), 2.50 (m overlap with DMSO, 2H, CH2).

後処理

  1. temperaturethe reaction mixture was then refluxed for 18 hours
  2. additionThe reaction mixture was poured onto ice-water
  3. extractionthe mixture was extracted with diethyl ether
  4. concentrationThe ether layer was concentrated under reduced pressure
  5. washThe acidic aqueous layer was washed with hexanes
  6. concentrationwas concentrated
  7. customto give a gummy residue
  8. customThe residue was crystallized from ethyl acetate/methanol
  9. customto provide 5.3 g
  10. customThe mother liquor was chromatographed on a silica gel column (Waters Associates-Prep. 500) with ethyl acetate/methanol (8:2)
  11. customto give an additional 2.55 g

出典と根拠

ORDレコード
ord-61089abff6df485792ee666b4adc3ea5
出典データセット
uspto-grants-1989_10
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US04871865

反応ノート

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