反応式
[C:1]1([Si:7]([C:10]2[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=2)(Cl)[Cl:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[CH3:16][Si:17]([CH3:20])([CH3:19])[OH:18].C(N(CC)CC)C>O1CCCC1>[CH3:16][Si:17]([CH3:20])([CH3:19])[O:18][Si:7]([C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)([C:1]1[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1)[Cl:8]参加物
実験手順
The following were ingredients were introduced into a stirrer-equipped four-neck flask: 164.8 g (651.2 mmol) diphenyldichlorosilane and 300 mL tetrahydrofuran. The resultant mixture was stirred at room temperature while a mixture of 60 g (542.7 mmol) of 81.4% pure trimethylsilanol and 65.9 g (651.2 mmol) of triethylamine was added dropwise. Stirring at room temperature was continued for an additional hour following completion of the addition, at which time the salt formed as a by-product of the reaction was removed by filtration. The filtrate was then distilled under reduced pressure to yield 118.7 g of a fraction boiling at 136.5° C.-142° C. under of 2 mm Hg, equivalent to a 71.4% yield of trimethylsiloxydiphenylchlorosilane. Analysis of this product by gas chromatography (GLC), nuclear magnetic resonance (NMR), and infrared spectrochemical analysis (IR) confirmed it to be trimethylsiloxydiphenylchlorosilane with the following structural formula. ##STR6##
後処理
- additionwere introduced into a stirrer-equipped four-neck flask
- additionwas added dropwise
- waitwas continued for an additional hour
- additioncompletion of the addition
- customat which time the salt formed as a by-product of the reaction
- customwas removed by filtration
- distillationThe filtrate was then distilled under reduced pressure
出典と根拠
- ORDレコード
- ord-d4d30c271a5a413ab29ed7fb832db57c
- 出典データセット
- uspto-grants-1994_11
- 特許番号
- US05364896
関連ノート
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