Maleic Anhydride → Furan-2,5-dione;5-methylidenebicyclo[2.2.1]hept-2-ene

HRID 23858

反応式

HRID 23858 の反応式
[C:1]1(=[O:7])[O:6][C:4](=[O:5])[CH:3]=[CH:2]1.O1[CH2:12][CH2:11][CH2:10][CH2:9]1>N(C(C)(C)C#N)=NC(C)(C)C#N.CCCCCC>[CH2:1]=[C:2]1[CH2:12][CH:11]2[CH2:4][CH:3]1[CH:9]=[CH:10]2.[C:4]1(=[O:5])[O:6][C:1](=[O:7])[CH:2]=[CH:3]1

参加物

5

反応物 2

HCID 7923Maleic AnhydrideHCID 8028Tetrahydrofuran

生成物 1

HCID 287853Furan-2,5-dione;5-methylidenebicyclo[2.2.1]hept-2-ene収率 183.7%

試薬・触媒・溶媒 2

HCID 6547Azobisisobutyronitrile触媒HCID 8058Hexane溶媒

実験手順

This synthesis example is directed to the synthesis of polymer (1b) (illustrated below as chemical formulas 14 or 15), a γ-hydroxy carboxylic acid structure. 21.2 g of 5-ethylenebicyclo[2.2.1]hept-2-ene, 19.6 g of maleic anhydride, 2.56 g of 2,2′-azobisisobutyronitrile, and 240 g of tetrahydrofuran were placed in a 500-ml, three-necked flask equipped with a thermometer, a condenser pipe, and a nitrogen inlet pipe, and the mixture was heated under reflux at 70C while introducing nitrogen for 8 hr to conduct polymerization. After the completion of the polymerization, the reaction mixture was poured into 1000 ml of n-hexane to precipitate the resultant polymer, which was then dried to give 37.5 g of a 5-methylenebicyclo[2.2.1]hept-2-ene/maleic anhydride copolymer (1a) (yield 92%). The polymer was analyzed by various methods and was found to mainly have a structure represented by the following formula:

後処理

  1. customequipped with a thermometer, a condenser pipe, and a nitrogen inlet pipe
  2. temperaturethe mixture was heated
  3. additionwhile introducing nitrogen for 8 hr
  4. custompolymerization
  5. customAfter the completion of the polymerization
  6. customto precipitate the resultant polymer, which
  7. customwas then dried

出典と根拠

ORDレコード
ord-798ec26d93734613be60fae168b8210e
出典データセット
uspto-grants-2005_02
特許番号
US06855483B2

関連ノート

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