Diethyl Ether → HCID 86638666、化合物

HRID 2389869ノート

反応式

HRID 2389869 の反応式
[O:1]1[C:9]2[CH:8]=[CH:7][N:6]=[CH:5][C:4]=2[CH2:3][CH2:2]1.[NH2:10][O:11][C:12]1[CH:17]=[CH:16][C:15]([N+:18]([O-:20])=[O:19])=[CH:14][C:13]=1[N+:21]([O-:23])=[O:22].C(OCC)C>C(#N)C>[N+:21]([C:13]1[CH:14]=[C:15]([N+:18]([O-:20])=[O:19])[CH:16]=[CH:17][C:12]=1[O-:11])([O-:23])=[O:22].[NH2:10][N+:6]1[CH:7]=[CH:8][C:9]2[O:1][CH2:2][CH2:3][C:4]=2[CH:5]=1

参加物

5

反応物 3

HCID 3283Diethyl EtherHCID 87140O-(2,4-dinitrophenyl)hydroxylamineHCID 155348962H,3H-furo(3,2-c)pyridine

生成物 1

HCID 86638666HCID 86638666、化合物収率 89%

試薬・触媒・溶媒 1

HCID 6342Acetonitrile溶媒

実験手順

To a solution of 2,3-dihydrofuro[3,2-c]pyridine (23.8 g, 200 mmol) in acetonitrile (130 mL) was added 1-(aminooxy)-2,4-dinitrobenzene (55.0 g, 240 mmol), and the mixture was stirred at room temperature for 3 days. Diethyl ether was added, and the resulting precipitate was collected by filtration to give the title compound (57.0 g, yield 89%).

後処理

  1. filtrationthe resulting precipitate was collected by filtration

出典と根拠

ORDレコード
ord-3803696f5b5b41f78877e96682917329
出典データセット
uspto-grants-2012_09
特許番号
US08273761B2

反応ノート

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