Acetone → Phthalonitrile
反応式
[N:1]1[C:8](Cl)=NC(Cl)=NC=1Cl.[OH-].[Na+].[CH3:12][C:13]([CH3:15])=O>>[C:8](#[N:1])[C:12]1[C:12](=[CH:13][CH:15]=[CH:15][CH:13]=1)[C:8]#[N:1]参加物
4
実験手順
A solution of intermediate D (32.7 g) in acetone (500 ml) was added to cyanuric chloride (18.5 g) in acetone (150 ml) at 0° C. and stirred at this temperature for 2 hours, maintaining the pH at 6 with 0.5M sodium hydroxide solution. The precipitated solid was filtered off, washed with ice cold water (2×250 ml) and dried to give the damp product (65.2 g).
後処理
- filtrationThe precipitated solid was filtered off
- washwashed with ice cold water (2×250 ml)
- customdried
出典と根拠
- ORDレコード
- ord-d4430ad981c0438e86a21e441f62dac7
- 出典データセット
- uspto-grants-2014_02
- 特許番号
- US08647425B2
反応ノート
読み込み中…