Acetone → Tributoxy(phenyl)silane

HRID 2416398

反応式

HRID 2416398 の反応式
C[CH:2](O)[CH3:3].C[C:6]([CH3:8])=O.[CH3:9][CH2:10]O[Si](OCC)(OCC)OCC.[C:22]1([Si:28]([O:35][CH2:36][CH3:37])([O:32][CH2:33][CH3:34])[O:29][CH2:30][CH3:31])[CH:27]=[CH:26][CH:25]=[CH:24][CH:23]=1.[N+]([O-])(O)=O.C(O)CCC.C(O)C>O>[C:22]1([Si:28]([O:35][CH2:36][CH2:37][CH2:2][CH3:3])([O:29][CH2:30][CH2:31][CH2:6][CH3:8])[O:32][CH2:33][CH2:34][CH2:9][CH3:10])[CH:23]=[CH:24][CH:25]=[CH:26][CH:27]=1

参加物

9

反応物 7

HCID 180Acetone2 回HCID 2631-ButanolHCID 702EthanolHCID 944Nitric AcidHCID 3776Isopropanol2 回HCID 6517TetraethoxysilaneHCID 13075Phenyltriethoxysilane

生成物 1

HCID 619663Tributoxy(phenyl)silane

試薬・触媒・溶媒 1

HCID 962Water溶媒2 回

実験手順

In a 1-liter flask 297 grams (4.798 moles) 2-propanol, 148 grams (2.558 moles) acetone, 73 grams (0.351 moles) TEOS, 45 grams (0.251 moles) MTEOS 121 grams (0.503 moles) phenyltriethoxysilane, 0.6 grams 0.1 M nitric acid and 72 grams (3.716 moles) deionized water were combined. The flask was refluxed for 4 hours. To the solution, 57 grams (0.769 moles) of Butanol, 88 grams (1.422 moles) 2-propanol, 44 grams (0.758 moles) of acetone, 59 grams (1.227 moles) of ethanol, 9.5 grams (0.528 moles) deionized water were added.

後処理

  1. temperatureThe flask was refluxed for 4 hours
  2. additionwere added

出典と根拠

ORDレコード
ord-8ce722781f1a48b09391700718c9cae0
出典データセット
uspto-grants-2004_11
特許番号
US06824879B2

関連ノート

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